Photographic developers containing a developing agent of the ascorbic acid type and an accelerator
AssigneeEastman Kodak Company
InventorsJacques Roussilhe, Siu-Chung Tsoi
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Abstract
The invention concerns a developer solution for processing silver halide photographic products. This developer solution contains an ascorbic acid developing agent, a auxiliary developing agent which is a substituted phenidone and a development accelerator which is a thioether having an ammonium group, a triazolium thiolate or a substituted thioalkane.
Claims9
An aqueous developer solution for the development of photographic silver halides, comprising a first silver halide developing agent that is an ascorbic acid, an auxiliary developing agent that is 1-phenyl-3-pyrazolidinone, and at least one development accelerator,
- wherein:
- (I) said auxiliary developing agent has the formula:
- ##STR17## wherein R.sup.1 to R.sup.7 in formula (I) each separately represent hydrogen, an alkyl group, a substituted or non-substituted alkoxy group, substituted or non-substituted aryloxy group, or a group represented by the formula:
- (X).sub.p --A-(Sol)
- wherein p is 0 or 1;
- X represents a divalent group chosen from
- --O--, --S--, and --NR.sup.8 --
- wherein R.sup.8 is H, an alkyl or A-(Sol);
- A represents a divalent group chosen from ##STR18## wherein q is between 0 and 5, and y is between 1 and 3;
- (Sol) is a solubilizing group chosen from:
- CO.sub.2 H, SO.sub.3 H, NHSO.sub.2 R.sup.10, SO.sub.2 NH.sub.2, SO.sub.2 NHR.sup.10, polyhydroxyalkyl, ##STR19## wherein R.sup.10 is an alkyl or aryl, R.sup.11 is OH, an alkyl or aryl, and R.sup.12 is hydrogen, an alkyl or aryl;
- with the additional conditions that
- (a) at least one of the radicals R.sup.1 to R.sup.7 must contain a (SOL) group, and
- (b) A can represent a covalent bond, and
- (II) said development accelerator is selected from the class consisting of:
- (a) thioethers having at least one ammonium group
- (b) triazolium thiolates, and
- (c) substituted thioalkanes.
Dependencies are inferred from the claim text.