Preparation of N-alkenyl carboxamides
AssigneeBASF SE
InventorsMarc Heider, Thomas Ruhl, Jochem Henkelmann
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AssigneeBASF SE
InventorsMarc Heider, Thomas Ruhl, Jochem Henkelmann
Estimating the term…
Preparation of N-alkenyl carboxamides of the general formula I ##STR1## in which the radicals R.sup.1 to R.sup.4 independently stand for hydrogen or for aliphatic, cycloaliphatic, or aromatic radicals, which optionally carry inert substituents, wherein an amide of the general formula II ##STR2## in which the radical R.sup.1 has the above meaning, and a carbonyl compound of the general formula III ##STR3## in which the radicals R.sup.2 to R.sup.4 have the above meanings, are caused to react in the presence of a base, said reaction being either a) carried out in the presence of a carboxylic acid derivative of the general formula IV ##STR4## in which the radical R.sup.5 stands for hydrogen or an alkyl or aryl group and X is a halogen, alkoxy, or carboxylalkyl radical, or b) continued in the presence of a carboxylic acid derivative of the formula IV, and the amide of the formula I is isolated.
A process for the preparation of an N-alkenyl carboxamide of the general formula I ##STR9## in which the radicals R.sup.1 to R.sup.4 independently stand for hydrogen or for aliphatic, cycloaliphatic, or aromatic radicals, which optionally carry inert substituents, wherein an amide of the general formula ##STR10## in which the radical R.sup.1 has the above meaning, and a carbonyl compound of the general formula III ##STR11## in which the radicals R.sup.2 to R.sup.4 have the above meanings, are caused to react in the presence of a base, said reaction being either
Dependencies are inferred from the claim text.