Process for the selective oxidation of aromatic compounds
AssigneeHoechst Aktiengesellschaft
InventorsWolfgang Anton Herrmann, Joao Domingos Galamba Correia, Richard Walter Fischer
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AssigneeHoechst Aktiengesellschaft
InventorsWolfgang Anton Herrmann, Joao Domingos Galamba Correia, Richard Walter Fischer
Estimating the term…
The invention relates to the use of compounds of the formula Re.sub.a O.sub.b X.sub.c L.sub.d, (I) in which X=F, Cl, Br, I or OH, L=Lewis base, a=an integer 1, 2 or 3 b=zero or an integer from 2 to 9, c=zero or an integer from 1 to 9, d=zero or an integer from 1 to 6, and the sum of a, b and c is such that it is appropriate to the zerovalency or trivalency to heptovalency of the rhenium with the proviso that if b is not equal to zero, b.gtoreq.2.multidot.a, as catalysts for the oxidation of electron-rich aromatic compounds and derivatives thereof and a process for the oxidation of electron-rich aromatic compounds, in which electron-rich C.sub.6 -C.sub.22 aryl compounds and derivatives thereof are oxidized in an organic solvent in the presence of a catalyst of the formula (I) and of a peroxide-containing compound.
A method of using compounds of the formula (I) as catalysts for the oxidation of electron-rich aromatic compounds and derivatives thereof, wherein the formula (I) is:
A process for oxidizing in an organic solvent electron-rich C.sub.6 -C.sub.22 -aryl compounds and derivatives thereof comprising the step of oxidizing the C.sub.6 -C.sub.22 -aryl compounds in the presence of a catalyst of the formula Re.sub.a O.sub.b X.sub.c L.sub.d (I), in which
Dependencies are inferred from the claim text.