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US 5,708,115 AGranted
Polymerization of vinyl monomers from silanes and siloxanes
AssigneeDow Corning Corporation
InventorsDaniel Graiver, Aaron Quoc Khieu, Binh Thanh Nguyen
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AssigneeDow Corning Corporation
InventorsDaniel Graiver, Aaron Quoc Khieu, Binh Thanh Nguyen
Estimating the term…
A method in which radical polymerization of a vinyl monomer is initiated by an ozonide group attached to a silane or a siloxane polymer. The method is particularly useful for preparing organic polymers having a silicone chain end, or for preparing wide ranges of silicone/organic polymers and copolymers with varied architecture, i.e., ABA block copolymers, comb polymers, star polymers, and hyper-branched polymers. In one embodiment, the method is carried out by simply heating a vinyl monomer in the presence of a silane containing ozonide functionality. The ozonide silane is obtained by exposing silanes or siloxanes having an alkyl group containing a double bond to ozone. Surprisingly, an ozonide attached to an organosilicon compound was found to be stable, and capable of initiating vinyl polymerization upon heating to moderate temperatures, i.e., about 70.degree. C.
A composition comprising an organosilicon compound containing ozonide functionality represented by the structure ##STR23## in which R is the residue of an unsaturated hydrocarbon radical containing at least two carbon atoms bound to silicon;
An organosilicon compound containing ozonide functionality prepared by a method comprising exposing to ozone an organosilicon compound selected from the group consisting of ##STR25## in which R is a hydrocarbon linking group containing at least two carbon atoms;
An organosilicon compound containing ozonide functionality prepared by a method comprising exposing to ozone an organosilicon compound selected from the group consisting of ##STR26## wherein m and n each have a value of 2-4;
A composition comprising an organosilicon compound containing ozonide functionality in which the organosilicon compound is a cycloalkyl silane selected from the group consisting of cycloalkyl silanes in which the silicon atom is part of a ring structure, and cycloalkyl silanes in which the silicon atom is not part of a ring structure but in which there are at least two carbon atoms between the silicon atom and the ozonide functionality, the organosilicon compound containing ozonide functionality being selected from the group consisting of ##STR27## wherein m and n each have a value of 2-4;
Dependencies are inferred from the claim text.