Apparatus for in situ, non-invasive polymer cure determination

An apparatus for determining an extent of curing of a cured polymer which comprises:

• (a) a detection means which measures a shift in fluorescence emission spectrum during polymerization of a liquid polymerizable composition to the cured polymer from a solvatochromic probe molecule, which is a polycyclic aromatic compound in an amount up to about 10.sup.-3 weight percent of the polymerizable composition, wherein the probe molecule has a first fluorescence emission spectrum in the liquid polymerizable composition and a shifted second fluorescence emission spectrum in the cured polymer, wherein the detection means includes a probe means mounted adjacent to the polymer for detecting the fluorescence;
• (b) a light source which can be directed at the polymerizable composition so that the fluorescence emission spectrum produced by the probe molecule is detected by the probe means;
• (c) a support for the fluid polymer during the curing to the cured polymer;
• and
• (d) calculating means for calculating at a given wavelength a ratio of the second fluorescence emission spectrum and the first fluorescence emission spectrum at least for the liquid polymerizable composition and during the polymerization to the cured polymer so that the extent of curing can be determined, and wherein the shift in the fluorescence is detected beyond a gel point of the polymer.