BF.sub.3 recovery process
AssigneeAmoco Corporation
InventorsRichard A. Holub, Scott D. Soltis, Cynthia W. Hermann
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AssigneeAmoco Corporation
InventorsRichard A. Holub, Scott D. Soltis, Cynthia W. Hermann
Estimating the term…
A process for the recovery of BF.sub.3 from crude oligomerization reaction product mixture containing dissolved BF.sub.3 is described, the process being characterized by vaporization of BF.sub.3 from the crude oligomerization reaction product mixture in a vaporization zone at a temperature insufficient to decompose BF.sub.3 or any BF.sub.3 promoter-complex in the mixture. BF.sub.3 from the vaporization zone is then contacted with a liquid olefin composition under conditions to absorb BF.sub.3, in an absorption zone, forming a mixture comprising liquid olefin composition and BF.sub.3. The liquid olefin composition may be utilized directly for oligomerization of the liquid olefin therein.
A process for the oligomerization of an olefin composition and recovery of BF.sub.3, comprising contacting an olefin composition in a reaction zone with BF.sub.3 and in the presence of a BF.sub.3 -promoter complex, under conditions to oligomerize said olefin, forming a crude polyolefin oligomerization reaction product mixture containing dissolved BF.sub.3 and BF.sub.3 -promoter complex;
A process for the oligomerization of a 1-decene composition and recovery of BF.sub.3 comprising contacting 1-decene composition in a reaction zone with BF.sub.3 and in the presence of a BF.sub.3 - promoter complex under conditions to oligomerize 1-decene, forming a crude polydecene reaction product mixture containing dissolved BF.sub.3 and BF.sub.3 - promoter complex;
Dependencies are inferred from the claim text.