Photo-removable electrophotographic toners using phenyl isopropenyl ketone
AssigneesToyo Ink Manufacturing Co., Ltd., Kazuyuki Sigita
InventorsKazuyuki Sugita, Ken-ichi Kishi, Hirofumi Iemura
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Abstract
Electrophotographic toners comprising a resin, a colorant, a charge controlling agent and an offset preventing agent. The resin comprises a copolymer containing at least one of phenyl isopropenyl ketone and its derivatives as a constituting monomer. The copolymer is photodegradable and thus the toners can be are used for recycling paper.
Claims8
An electrophotographic toner comprising a resin, a colorant, a charge-controlling agent and an offset-preventing agent, wherein the resin comprises:
- a copolymer of a plurality of monomers, one of said monomers being phenyl isopropenyl ketone or a substituted phenyl isopropenyl ketone in which at least one hydrogen atom of the phenyl group is substituted with alkyl, alkoxy, alkoxycarbonyl, or acyl, each of which has 1-4 carbon atoms, halogen, cyano, nitro, amino, hydroxy, or carboxy, said monomers further comprising styrene and alkyl acrylate, wherein the molar ratio of phenyl isopropenyl ketone or substituted phenyl isopropenyl ketone to styrene monomer to alkyl acrylate monomer is 30-40:20-50:15-50;
- and
- a polyester resin, wherein the amount of said copolymer is 30% or more by weight of the weight of said copolymer plus said polyester resin, wherein said toner is removable from a printing material onto which said toners are electrophotographically fixed, by irradiation with light.
An electrophotographic toner which can be fixed onto a printing material and can be subsequently removed from the printing material by use irradiating with light and which comprises:
- a copolymer of monomers, one of said monomers being phenyl isopropenyl ketone or a substituted phenyl isopropenyl ketone in which at least one hydrogen atom of the phenyl group is substituted with alkyl, alkoxy, alkoxycarbonyl, or acyl, each of which has 1-4 carbon atoms, halogen, cyano, nitro, amino, hydroxy, or carboxy, said monomers further comprising styrene and alkyl acrylate, wherein the molar ratio of phenyl isopropenyl ketone or substituted phenyl isopropenyl ketone to styrene monomer to alkyl acrylate monomer is 30-40:20-50:15-50;
- a polyester resin, wherein the amount of said polyester resin is 70% or less by weight of the weight of said polyester resin plus said copolymer;
- one or more colorants, at least one of which being selected from the group consisting of phthalocyanine, quinacridone, benzidine, rhodamine, insoluble azo compounds, carbon black, and blue black pigments;
- one or more photosensitizers selected from the group consisting of Michler's ketone, 4,4'-bis(diethylamino)-benzophenone, thioxanthones, N-phenylglycine, N-methylpyrrolidone, 1,2,3-triphenylguanidine, N,N-dimethylaniline, piperidine, triethylamine, and dimethylaminoethanol;
- and
- a wax as an offset-preventing agent.
Dependencies are inferred from the claim text.