A process for producing a carbon structural thermal insulator, and comprising, preparing a suspension of discrete carbon fibers by mixing said fibers while agitating said fibers in a dispersive liquid, each of said discrete carbon fibers being made of a plurality of discrete filaments, molding a preform and orienting said discrete filaments, eliminating part of said dispersive liquid, and baking said preform in a mold, wherein said dispersive liquid is a non-water-containing viscoplastic liquid having a good wettability compared to components of said suspension, during preparation of said suspension said carbon fibers are mixed and agitated in said viscoplastic liquid until the fibers separate into said filaments such that said filaments are uniformly distributed by carbonizing said viscoplastic dispersive liquid in said preform, a porous structure of coke residue is formed on said filaments and additional rigidity is given to said preform after molding and baking of said preform by depositing pyrolytic carbon in the porous structure of said preform.