ZnS:Cu electroluminescent phosphor and method of making same
AssigneeOsram Sylvania Inc.
InventorsVaddi Butchi Reddy, Kenneth T. Reilly
Life of this patent
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Abstract
A improved ZnS:Cu electroluminescent phosphor having a halflife of at least about 900 hours. The halflife improvement is made by doping the phosphor with minor amounts of gold and substantially increasing the amount of low intensity milling between firing steps. The improved phosphor has a dramatically longer halflife without sacrificing brightness or exhibiting large shifts in emission color.
Claims24
An electroluminescent phosphor having the general formula ZnS:Cu,Cl,Au, a halflife of at least about 900 hours, and x and y color coordinates where the x color coordinate is from about 0.156 to about 0.196 and the y color coordinate is from about 0.370 to about 0.430.
A method for increasing the halflife of a ZnS:Cu electroluminescent phosphor comprising:
- blending amounts of zinc sulfide, a copper source, a gold source and a chloride flux to form a mixture;
- firing the mixture at a temperature from about 900.degree. C. to about 1400.degree. C. for about 2 hours to about 8 hours to form a zinc sulfide material containing copper, chlorine and gold;
- subjecting the zinc sulfide material to a low intensity milling for between about 190 minutes to about 280 minutes to form a milled material;
- blending the milled material with an amount of zinc sulfate and an amount of copper sulfate;
- and
- refiring the blended milled material at a temperature from about 500.degree. C. to about 1000.degree. C. for about 1 to 5 hours to form an electroluminescent phosphor.
An electroluminescent lamp comprising:
- a first electrode, a first layer of dielectric material adjacent to the first electrode, a second layer of a dielectric material adjacent to the first layer;
- the second layer containing an electroluminescent phosphor having a general formula ZnS:Cu,Cl,Au, a halflife of at least about 900 hours, and x and y color coordinates where the x color coordinate is from about 0.156 to about 0.196 and the y color coordinate is from about 0.370 to about 0.430;
- and
- a second electrode adjacent to the second layer of dielectric material.
Dependencies are inferred from the claim text.