Vacuum pressure swing adsorption process

In a vacuum pressure swing adsorption process for the separation of a less readily adsorbable component of a feed gas mixture containing said component and a more readily adsorbable component in an adsorption system having two or more adsorbent beds containing adsorbent material capable of selectively adsorbing the more readily adsorbable component of said feed gas mixture, said process being carried out in each adsorbent bed, on a cyclic basis, and comprising the following steps:

• (a) introducing a feed gas mixture to a feed end of the adsorbent bed while product gas is simultaneously added to a product end of the bed, the bed being pressurized thereby from a lower intermediate rising pressure to an intermediate pressure;
• (b) passing the feed gas mixture to the feed end of the bed to increase the pressure of the bed from the intermediate pressure to an upper adsorption pressure, with recovery of less readily adsorbable component from the product end of the bed during or at the end of said increase in pressure of the bed;
• (c) cocurrently depressurizing the bed from the upper adsorption pressure to an intermediate falling pressure, with passage of gas from the product end of the bed for use as pressure equalization gas in another bed in the system;
• (d) countercurrently depressurizing the bed, with the evacuation of said more readily adsorbable component from the feed end thereof, thereby reducing the pressure of the bed from the intermediate falling pressure to a lower, subatmospheric desorption pressure;
• and
• (e) discharging additional quantities of gas from the feed end of the bed, while simultaneously introducing said less readily adsorbable component to the product end of the bed, the pressure of the bed increasing from said lower, subatmospheric desorption pressure to the intermediate rising pressure, the improvement comprising:
• (1) following step (c) and prior to step (d), countercurrently depressurizing the bed, with discharge of gas from the feed end thereof, while simultaneously cocurrently depressurizing the bed with passage of gas from the product end thereof for use as pressurization gas in a bed in the system undergoing repressurization, the bed pressure decreasing from the intermediate falling pressure to a lower intermediate falling pressure;
• and
• (2) following step (d) and prior to step (e), discharging said more readily adsorbable component from the feed end of the bed, while simultaneously introducing said less readily adsorbable component as purge gas to the product end of the bed, the pressure of the bed remaining essentially at said lower, subatmospheric desorption pressure,
• whereby the productive capacity of the adsorption system is increased and the efficiency of the overall process is enhanced.