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US 5,700,295 AGranted
UV absorbers, their preparation and the use thereof
AssigneeCiba Specialty Chemicals Corporation
InventorsFrancesco Fuso, Gerhard Reinert
Life of this patent
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Abstract
The invention relates to compounds of formula ##STR1## wherein the variables have the meanings given in the claims. The compounds are suitable for use as UV absorbers for the photochemical stabilisation of undyed, dyed or printed textile fiber materials and for enhancing the sun protection factor thereof.
Claims14
A compound of formula ##STR46## wherein B.sub.1 and B.sub.2 are each independently of the other an aliphatic linking group,
- U is the radical of formula ##STR47## wherein (L.sub.1).sub.1-3 is 1 to 3 radicals L.sub.1 selected from the group consisting of sulfo, hydroxy, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.12 alkoxy and (L.sub.2).sub.0-1 is 0 to 1 substituents L.sub.2 selected from the group consisting of sulfo, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.12 alkoxy,
- W is a group --NR.sub.2 --, --O-- or --S--,
- R.sub.2 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl,
- W.sub.1 is a radical --C(O)O--, --O(O)C--, --C(O)NH-- or --HN(O)C--,
- .dbd.E-- is a group .dbd.N-- or .dbd.C(T.sub.1)--, and T.sub.1 is halogen, C.sub.1 -C.sub.4 alkylsulfonyl, formyl, C.sub.2 -C.sub.4 alkoxycarbonyl or cyano,
- X.sub.1 is halogen, hydroxy, sulfo, C.sub.1 -C.sub.4 alkylsulfonyl, phenylsulfonyl, unsubstituted or substituted amino, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl,
- T independently has one of the meanings given for X.sub.1 or is an alkoxy, aryloxy, alkylthio or arylthio radical, or is a nitrogen-containing heterocyclic radical or is a reactive radical of formula ##STR48## R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by hydroxy, sulfo, sulfato, carboxy or cyano, or is a radical ##STR49## R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.4 is hydrogen, hydroxy, sulfo, sulfato, carboxy, cyano, halogen, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkanoyloxy, carbamoyl or the group --SO.sub.2 --Y,
- alk and alk' are each independently of the other C.sub.1 -C.sub.6 alkylene,
- arylene is a phenylene or naphthylene radical which is unsubstituted or substituted by sulfo, carboxy, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,
- Y is vinyl or a radical --CH.sub.2 --CH.sub.2 --Z and Z is a leaving group,
- W.sub.2 is --O-- or --NR.sub.3 --,
- W.sub.3 is a group --SO.sub.2 --NR.sub.1 --, --CONR.sub.1 -- or --NR.sub.1 CO--, and
- r, s, t and u are each independently of one another 0 or 1, s being 0 when t is 0,
- with the proviso that the compound of formula (1) carry at least one sulfo or sulfato group and at least one group which is removable under alkaline conditions.
11 more elements
Dependencies are inferred from the claim text.