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US 5,691,394 AGranted
Photopolymerizable composition containing a sensitizing dye and a titanocene compound
AssigneeFuji Photo Film Co., Ltd.
InventorSyunichi Kondo
Life of this patent
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Abstract
A photopolymerizable composition is disclosed, comprising an addition polymerizable compound having at least one ethylenically unsaturated double bond, a sensitizing dye represented by formula (I) and a titanocene compound. The photopolymerizable composition exhibits high sensitivity to active light rays over a wide region of from ultraviolet light to visible light.
Claims16
A photopolymerizable composition comprising:
- (a) an addition polymerizable compound having at least one ethylenically unsaturated double bond;
- (b) a sensitizing dye represented by the following formula (I);
- and (c) a titanocene compound:
- ##STR47## wherein R.sup.1 and R.sup.2, which are the same or optionally are different, each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkenyl group, a substituted alkenyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an alkynyl group or a substituted alkynyl group;
- A represents an oxygen atom, a sulfur atom, a carbon atom substituted by an alkyl group or an aryl group or a carbon atom substituted by two alkyl groups;
- X represents a nonmetallic atom group necessary for forming a nitrogen-containing heterocyclic 5-membered ring;
- Y represents a phenyl group, a substituted phenyl group or an unsubstituted or substituted heteroaromatic ring;
- Z represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, an alkylthio group, an arylthio group, a substituted amino group, an acyl group or an alkoxycarbonyl group;
- and
- Z and Y optionally are combined with each other to form a ring.
7 more elements
Dependencies are inferred from the claim text.