Radiation sensitive resin composition containing quinone diazide ester having two hindered phenol groups
AssigneeJapan Synthetic Rubber Co., Ltd.
InventorsKatsumi Inomata, Masahiro Akiyama, Toshiyuki Ota, Akira Tsuji
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Abstract
The present invention provides a radiation sensitive resin composition which contains an alkali soluble resin and a 1,2-quinonediazide compound represented by the following formula, for example. ##STR1## The radiation sensitive resin composition of the present invention has an excellent developability, provides an excellent pattern shape, is superior in sensitivity and resolution, and has greatly improved focus latitude and heat resistance in particular. Therefore, the radiation sensitive resin composition of the present invention can be suitably used as a resist for the production of LSIs.
Claims18
A radiation sensitive resin composition containing, in admixture, an alkali soluble resin and a radiational effective amount of at least one 1,2-quinonediazide compound selected from the group consisting of compounds represented by the following formula (1):
- ##STR17## wherein R.sup.1 is an alkyl group having 1 to 3 carbon atoms, a cycloalkyl group, an alkoxyl group having 1 to 3 carbon atoms or an aryl group;
- D is an organic radical having a 1,2-quinonediazide group;
- a is 1;
- b is an integer of 0 to 4;
- A is a single bond, a polymethylene group having 1 to 4 carbon atoms, a cycloalkylene group, a phenylene group, a group represented by the following formula (2):
- ##STR18## a carbonyl group, an ester group, an amide group or an ether group;
- Y is a hydrogen atom, an alkyl group or an aryl group;
- and X.sup.1 and X.sup.2 are the same or different and represented by the following formula (3):
- ##STR19## wherein each of Z.sup.1, Z.sup.2 and Z.sup.3 is the same or different and is an alkyl group, a cycloalkyl group or an aryl group;
- R.sup.2 is an alkyl group, a cycloalkyl group or an alkoxyl group;
- and f is an integer of 0 to 3. ##STR20##
A radiation sensitive resin composition containing, in admixture, an alkali soluble resin and a radiational effective amount of at least one 1,2-quinonediazide compound selected from the group consisting of compounds represented by the following formula (4):
- ##STR22## wherein R.sup.1 is an alkyl group having 1 to 3 carbon atoms, a cycloalkyl group, an alkoxy group having 1 to 3 carbon atoms or an aryl group;
- D is an organic radical having a 1,2-quinonediazide group;
- a is 1;
- b is an integer of 0 to 4;
- and X.sup.1 and X.sup.2 are the same or different and represented by the following formula (3):
- ##STR23## wherein each of Z.sup.1, Z.sup.2 and Z.sup.3 is the same or different and is an alkyl group, a cycloalkyl group or an aryl group;
- R.sup.2 is an alkyl group, a cycloalkyl group or an alkoxyl group;
- and f is an integer of 0 to 3.
Dependencies are inferred from the claim text.