A process for in situ electroforming a structural reinforcing layer of metal bonded to an internal wall of a degraded section of metal tube made of iron, copper, nickel or an alloy comprising any of iron, copper and nickel, comprising:
- mechanically cleaning the internal tube wall surface in said tube section;
- inserting a probe into the metal tube and moving it so that it spans the degraded tube section, the probe having an electrode extending substantially along its length, sealing means at one or both ends for containment of fluids within the tube section, and circulation means for flowing fluids into and out of the tube section;
- and
- electroforming a structural layer of metal on the internal wall of the degraded tube section by flowing an electrolyte containing a major amount of ionic nickel and a minor amount of a suitable ionic form of at least one element of interest consisting of the group:
- manganese, molybdenum, copper, tungsten, iron and phosphorus through the section and applying a pulsed direct current between the electrode and the metal tube at a pulse frequency of 10 to 1000 Hz with a duty cycle in the range 10 to 60% for a sufficient time to electroform a metal layer 0.1 to 2 mm thick, so that the tube section is restored to its original mechanical properties, said structural electroformed layer having an ultrafine grain microstructure which provides the layer with a high degree of hardness, stiffness and strength while maintaining excellent ductility.