Process for producing an organic electroluminescence device

A process for producing an organic electroluminescent device, comprising

• (a) preparing a laminated structure including at least a light-emitting layer formed of a luminescent organic solid which is disposed between mutually opposing positive and negative electrodes, the luminescent organic solid being implantable with electrons from the negative electrode and holes from the positive electrode when direct current is charged between the positive electrode and the negative electrode and thereby having an excited state therein to recombine the electrons and the holes injected into the luminescent organic solid for light emission, and
• (b) depositing a film of an electrically insulating polymer compound as a protection layer on an outer surface of the laminated structure, the electrically insulating polymer compound being selected from the group consisting of (i) a fluorine-free polymer compound selected from the group consisting of polyethylene, polypropylene, polystyrene, polymethyl methacrylate, polyurea and polyimide, (ii) a compound having a molecular weight not less than 400 selected from the group consisting of polytetrafluoroethylene, polychlorotrifluoroethylene, polydicholorodifluoroethylene and a copolymer of chlorotrifluoroethylene and dichlorodifluoroethylene and (iii) a fluorine-containing copolymer having a main chain including a cyclic structure, wherein a deposition source of the electrically insulating polymer is heated to a temperature of not more than 600.degree. C. and the protection layer is deposited at a rate of not more than 50 nm/second,
• wherein said layers beginning from a layer directly disposed on a lower electrode of said positive and negative electrodes and continuing to said protection layer are disposed without breaking a vacuum environment in a vacuum chamber and where the pressure in the vacuum chamber is maintained at not more than 1.times.10.sup.-2 Pa prior to each of said layers being disposed.