Positive photoresist composition containing a dissolution inhibitor and a dye in an organic solvent

A positive photoresist composition which comprises an effective amount of a compound A in admixture with a dissolution inhibitor and an organic solvent, wherein said compound A is a compound selected from the group consisting of:

• (1) cyan dyes of formula (I)
• (SO.sub.3 M).sub.h --[Pc]--(SO.sub.2 --NH--R).sub.i (I)
• wherein Pc is phthalocyanine nucleus, h and i are the average substitution number of SO.sub.3 M and SO.sub.2 --NH--R respectively, R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group and SO.sub.3 M is a sulfonic acid or a sulfonic acid salt provided that h+i<4, h<3 and i+l-4;
• (2) azo dyes represented by formula (II)
• A--N=N--B--(--N=N--D--).sub.k --N=N--E (II)
• wherein each of A, B, D and E is independently a benzene or naphthalene ring which is unsubstituted or is substituted by --SO.sub.2 --NH--R and/or --CO--NH--R and k is 0 or 1, provided that at least one of the A, B, D and E is a benzene-or naphthalene ring which is substituted by --SO.sub.2 --NH--R and/or --CO--NH--R;
• and R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group;
• (3) yellow dyes represented by formula (III)
• G--J--M' (III)
• wherein M' is a group represented by the following formula ##STR20## wherein each of R.sub.3 --R.sub.5 is independently a hydrogen atom, an alkyl group, a halogen atom, a sulfonic acid group, a sulfonic acid salt group or --SO.sub.2 --NH--R, provided that at least one of the R.sub.3 --R.sub.5 is --SO.sub.2 --NH--R, R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group,
• J is a crosslinking group represented by one of the following formula ##STR21## wherein each of R.sub.6 --R.sub.14 is independently a hydrogen atom, an alkyl group, a halogen atom, a sulfonic acid group, a sulfonic acid salt group or --SO.sub.2 --NH--R, R is as defined above,
• G is M', a hydrogen atom or a phenylazophenyl, napthylazophenyl or phenylazonaphthyl group and R is as defined above;
• (4) magenta dyes represented by formula (IV) ##STR22## wherein each of R.sub.15 --R.sub.18 is independently a hydrogen atom, an alkyl or aryl group which is unsubstituted or is substituted with --SO.sub.2 --NH--R, each of R.sub.19 --R.sub.21 is independently a hydrogen atom, an alkyl group or aryl group which may be substituted with --SO.sub.2 --NH--R, a sulfonic acid group, a sulfonic acid salt group or --SO.sub.2 --NH--R, provided that at least one of the R.sub.19 --R.sub.21 is --SO.sub.2 --NH--R, and R is an alkyl, cycloalkyl, alkyl carbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group
• (5) dyes represented by formula (V) ##STR23## wherein m and n are the average substitution number of SO.sub.3 M and SO.sub.2 --NH--R, both of which are substituents of anthraquinone ring, respectively, and m and n are 0-4 and 1-6 respectively provided that m+n<6, R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group;
• (6) dyes represented by formula (VI) ##STR24## wherein each of A' and B' is independently a hydrogen atom, an alkyl group or an aryl group which substituted with SO.sub.2 --NH--R or SO.sub.3 M, provided that both of A' and B' are not hydrogen atoms at the same time, m' and n' are the average substitution number of SO.sub.3 M and SO.sub.2 --NH--R, both of which may be substituted on only one of the A' and B', on both A' and B' or on the anthraquinone ring, and m' and n' are integers of 0-2 and 1-3 respectively provided that m'+n'<3, R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group, and SO.sub.3 M is a sulfonic acid or a sulfonic acid salt;
• and
• (7) compounds represented by the following formulae:
• ##STR25## wherein R is an alkyl, cycloalkyl, alkylcarbonylaminoalkyl, alkylcarbonylamino, cyclohexylalkyl, alkoxy, alkoxyalkyl, aryl, aralkyl or alkylcarbonyloxy group, each of B.sub.1 and B.sub.8 is independently a hydrogen atom or lower alkyl, each of B.sub.2 to B.sub.7 is independently a carboxylic acid group, a carboxylic acid salt group, a sulfonic acid group, a sulfonic acid salt group, a hydroxy group, a lower alkyl group or a hydrogen atom and each of k' and j', which are the substitution number of --SO.sub.2 --NH--R and --CO'NH--R respectively, is independently 0-3, provided that k'+j'<1, and ##STR26##