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US 5,352,831 AGranted
Oligomeric cyanoguanidines
AssigneeCiba-Geigy Corporation
InventorsPeter Flury, Martin Roth, Sameer H. Eldin
Life of this patent
Estimating the term…
Abstract
Oligomeric cyanoguanidines of formula I ##STR1## wherein, for example, R.sup.1 and R.sup.2 are each phenyl, R is 1,4-phenylene and n is an integer from 1 to 20, are suitable latent hardeners for epoxy resins. They are readily soluble in solvents suitable for the application of epoxy resins, and the cured products obtained therewith have a high glass transition temperature.
Claims8
An oligomeric cyanoguanidine of formula I ##STR13## wherein R is a divalent C.sub.2 -C.sub.20 aliphatic hydrocarbyl, mono- or polynuclear C.sub.5 -C.sub.20 cycloaliphatic, C.sub.6 -C.sub.20 aromatic radical;
- or
- R is a divalent radical of furan, pyran, pyridine, pyrrole, imidazole or thiophene;
- or
- R is a group of formula II ##STR14## wherein T is methylene, isopropylidene, CO, O, S or SO.sub.2 ;
- R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.6 -C.sub.10 aryl, C.sub.7 -C.sub.2 aralkyl or a monovalent radical of furan, pyran, pyridine, pyrrole, imidazole or thiophene;
- and,
- n is an integer from 1 to 20,
- which radicals R, R.sup.1 and R.sup.2 are unsubstituted or are substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, nitro, halogen, R.sup.3 OCO or R.sup.3 COO, where R.sup.3 is phenyl or C.sub.1 -C.sub.4 alkyl,
- with the proviso that 1,6-hexane-bis(3-cyano-2-isobutylguanidine) is excluded.
6 more elements
Dependencies are inferred from the claim text.