Black-and-white silver halide photographic light-sensitive material and a method for processing the same
AssigneeKonica Corporation
InventorsSatomi Kawasaki, Shyouji Nishio, Hideki Komatsu
Life of this patent
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Abstract
A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide photographic emulsion layer and a protective layer in that order, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and said emulsion layer contains a hydrazine derivative or a compound represented by the following formula (T): ##STR1##
Claims15
A silver halide photographic light-sensitive material comprising a support, a silver halide photographic emulsion layer and a protective layer, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and a compound represented by the following formula (T) or a hydrazine compound selected from the group consisting of the following formulae H-a, H-b, H-c and H-d:
- ##STR60## wherein R.sub.1, R.sub.2, and R.sub.3 each represent a hydrogen atom or a substituent;
- and X represents an anion;
- formula H-a ##STR61## wherein R.sub.23 and R.sub.4 each represent a hydrogen atom, an alkyl group, a phenyl group, a naphthyl group, a cyclohexyl group, a pyridyl group, or a pyrrolidyl group;
- R.sub.25 represents a hydrogen atom, a benzyl group, an alkyl group or an alkoxy;
- Y is a sulfur atom or an oxygen atom;
- R.sub.26 and R.sub.27 each represent a divalent aromatic group;
- L represents a divalent linkage group;
- R.sub.28 is --NR'R" or --OR.sub.29, wherein R', R" and R.sub.29 each are a hydrogen atom, an alkyl group, a phenyl group, a naphthyl group, or a heterocyclic group, provided that R' and R" may combine together with a nitrogen atom to form a ring;
- and m and n each are an integer of 0 or 1;
- ##STR62## wherein R.sub.5, R.sub.6 and R.sub.7 each represent a hydrogen atom, an alkyl group, a phenyl group, a naphthyl group, a cyclohexyl group, a pyridyl group, a pyrrolidyl group, an alkoxy group or an aryloxy group;
- Z is a sulfur atom or an oxygen atom;
- R.sub.9 represents an alkyl group, an alkoxy or an amino group, they may have a substituent of an alkoxy, cyano or aryl group;
- and R.sub.8 represents a divalent aromatic group;
- ##STR63## wherein A represents an aryl group or a heterocyclic group containing a sulfur atom or an oxygen atom;
- R.sub.10 and R.sub.20 each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, a hydroxy group or a heterocyclicoxy group, provided that either one of R.sub.10 and R.sub.20 represents an alkenyl group, an alkynyl group, a saturated heterocyclic group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, a hydroxy group or a heterocyclicoxy group;
- R.sub.30 represents an alkynyl group or a saturated heterocyclic group, and H in --NHNH-- of formulae H-c and H-d may be substituted by a substituent.
A method for processing a silver halide photographic light-sensitive material comprising a support and provided thereon, a silver halide photographic emulsion layer and a protective layer in that order, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and said silver halide photographic emulsion layer contains a hydrazine derivative or a compound represented by the following formula (T), comprising the steps of:
- exposing said material, and
- developing the exposed material with a developer in the presence of a cyclodextrin compound, ##STR66## wherein R.sub.1, R.sub.2, and R.sub.3 each represent a hydrogen atom or a substituent;
- and X represents an anion.
Dependencies are inferred from the claim text.