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US 5,352,499 AGranted
Multilayered structures comprising polycarbonate layers and functionalized polyamide layer
AssigneeGeneral Electric Company
InventorG. Fred Willard
Life of this patent
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Abstract
Multilayered structures comprising polycarbonate layers and functionalized polyamide layers exhibit adhesion to each other without the use of a tie layer. The multilayered structures are useful in containers requiring the combined properties of high impact strength and chemical resistance and/or oxygen barrier resistance.
Claims7
A multilayered bonded laminated structure comprising:
- (a) an aromatic polycarbonate resin layer;
- and
- (b) a polyamide resin layer exhibiting gas barrier properties, said polyamide resin comprising the reaction product of:
- (i) a dicarboxylic acid,
- (ii) a diamine, and
- (iii) an effective amount comprising at least about 3 mole percent of (iii) based on total moles of (ii) and (iii) of a polyamine of the general formula:
- ##STR11## wherein R.sub.6 and R.sub.7 are independently selected from aliphatic, aromatic, and unsaturated hydrocarbons and n is an integer of from 1 to 6, and m is an integer from 1 to 6 said polyamine containing an internal amine group which is less reactive than the terminal amine groups and said polyamine having a concentration greater than approximately 1% of the dicarboxylic acid concentration, based on total moles of dicarboxylic acid, said layers (a) and (b) being in direct adhesive contact with each other without the use of a tie layer therebetween.
4 more elements
Dependencies are inferred from the claim text.