Thermosetting coating compositions
AssigneeEastman Chemical Company
InventorsThauming Kuo, Charles H. Foster
Life of this patent
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Abstract
Provided are polyester resins containing hydroxy functionalized isophthalate ester moieties useful in coating compositions. The invention provides both solvent-borne as well as water-borne coating compositions comprised of the resins and a crosslinker such as a melamine-type crosslinker. Polyester resins of the present invention having a T.sub.g of greater than about 50.degree. C. are useful in thermosetting powder coating compositions. The coatings thus provided possess excellent acid resistance, hardness, impact resistance, and stain resistance.
Claims6
A curable polyester having a number average molecular weight of about 800 to about 6,000 and a weight average molecular weight of about 3,000 to about 40,000, comprising
- (a) about 20 to about 60 mol % of diol residues, based on the total moles of components (a), (b), (c), (d), (e) and (f);
- (b) 3.5 to about 20 mol % of polyol residues, based on the total moles of components (a), (b), (c), (d), (e) and (f);
- wherein said polyol residues are selected from the group consisting of trimethylolpropane, trimethylolethane, glycerol, 2,2-bis(hydroxymethyl)-1,3-propanediol, 1,2,3,4,5,6-hexahydroxyhexane, and bis(2,2-bis(hydroxymethyl)-3-propanol ether;
- (c) about 5 to about 40 mol % of hydroxy functionalized isophthalic acid residues, based on the total moles of (a), (b), (c), (d), (e) and (f);
- said hydroxy functionalized residues having the formula ##STR7## wherein X is selected from --O--, --S--, --SO.sub.2 -- or --O--(CH.sub.2 --).sub.n wherein n is 1 to about 6;
- R is a phenyl radical containing 1-3 hydroxy groups with the proviso that when X is --O-- or --S--, that R may also be hydrogen;
- (d) about 10 to about 40 mol % of diacid residues, derived from an aromatic diacid or a cycloaliphatic diacid or a mixture thereof, based on the total moles of (a), (b), (c), (d), (e) and (f);
- (e) about 0 to about 40 mol % of diacid residues derived from an aliphatic diacid based on the total moles of components (a), (b), (c), (d), (e) and (f);
- (f) 0 to about 10 mol % of residues derived from trimellitic acid or trimellitic anhydride, based on the total moles of components (a), (b), (c), (d), (e) and (f).
Dependencies are inferred from the claim text.