Process for separating catalysts from organic solutions, by means of semipermeable membranes
AssigneeEniricerche S.p.A.
InventorsNunzio Andriollo, Giorgio Cassani, Paolo D'Olimpio, Bruno Donno, Marco Ricci
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Abstract
Disclosed is a process for separating metal catalysts based on ammonium and phosphonium phosphotungstates from reaction mixtures in which they are dissolved. The process is based on the use of semipermeable membranes and has found an useful application in the separation of the above said catalysts from mixtures obtained from alkenes and soybean oil epoxidation.
Claims18
An ultrafiltration process for separating catalyst(s) from an organic solution in which the catalyst or catalysts are dissolved, the catalyst(s) consisting essentially of phosphotungstates or arsenotungstates as an anionic portion and ammonium or phosphonium salts as a counter-ion having surfactant characteristics, which process comprises the step of passing the catalyst-containing organic solution through an ultrafiltration membrane having an exclusion molecular weight sufficient to retain some of the catalyst(s) and to form, as a permeate, an organic solution containing a reduced concentration of the dissolved catalyst(s) and, as a retenate, an organic solution having an increased concentration of the dissolved catalyst(s).
Dependencies are inferred from the claim text.