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AssigneeJapan Synthetic Rubber Co., Ltd.
InventorsMinoru Kato, Teruo Hiraharu, Koichi Nishiwaki, Hiroshi Tadenuma
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An aqueous fluorine-containing polymer dispersion having particle diameters of 0.05-3 .mu.m, which is obtainable by emulsion-polymerizing 5-95 parts by weight of a monomer mixture consisting of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-18 carbon atoms and alkyl methacrylates whose alkyl groups have 1-18 carbon atoms and optionally an ethylenically unsaturated compound copolymerizable with the alkyl acrylates and the alkyl methacrylates, in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer; and an aqueous dispersion containing a fluorine-containing polymer which consists essentially of 95-30 parts by weight (in terms of solids content) of said aqueous fluorine-containing polymer dispersion and 5-70 parts by weight (in terms of solids content) of an aqueous dispersion of a water-soluble resin and/or a water-dispersible resin. The aqueous fluorine-containing polymer dispersion and the aqueous dispersion containing a fluorine-containing polymer have excellent heat resistance and weather resistance inherent in fluororesins and are significantly improved in film formability, transparency and adhesion to substrate. Therefore, these aqueous dispersions can be used as a coating composition for various applications, a fiber-treating compound, a paper-processing compound or a floor-coating compound.
An aqueous fluorine-containing polymer dispersion having average particle diameters of 0.05-3 .mu.m, which is obtained by emulsion-polymerizing 5-95 parts by weight of a monomer mixture of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-8 carbon atoms and alkyl methacrylates whose alkyl groups have 1-8 carbon atoms in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer, said monomer mixture being absorbed into the vinylidene fluoride polymer particles and the proportion of the alkyl acrylate in the monomer mixture being less than 80% by weight, wherein the vinylidene fluoride polymer is obtained by emulsion polymerization and is a vinylidene fluoride/tetrafluoroethylene copolymer or a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene copolymer.
A process for producing an aqueous fluorine-containing polymer dispersion, which comprises emulsion-polymerizing 5-95 parts by weight of a monomer mixture consisting of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-18 carbon atoms and alkyl methacrylates whose alkyl groups have 1-18 carbon atoms and optionally an ethylenically unsaturated compound copolymerizable with the alkyl acrylates and the alkyl methacrylates, in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer, wherein the vinylidene fluoride polymer is obtained by emulsion polymerization and is a vinylidene fluoride/tetrafluoroethylene copolymer or a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene copolymer.
An aqueous dispersion containing a fluorine-containing polymer, which dispersion consists essentially of 95-30 parts by weight (in terms of solids content) of the aqueous fluorine-containing polymer dispersion of claim 1 and 5-70 parts by weight (in terms of solids content) of an aqueous dispersion of at least one resin selected from the group consisting of a water-soluble resin and a water-dispersible resin.
An aqueous fluorine-containing polymer dispersion having average particle diameters of 0.05-3 .mu.m, which is obtained by emulsion-polymerizing 5-95 parts by weight of a monomer mixture of at least one monomer selected from the group consisting of alkyl acrylates whose alkyl groups have 1-8 carbon atoms and alkyl methacrylates whose alkyl groups have 1-8 carbon atoms, and an ethylenically unsaturated compound copolymerizable with the alkyl acrylates and the alkyl methacrylates in an aqueous medium in the presence of 100 parts by weight of particles of a vinylidene fluoride polymer, said monomer mixture being absorbed into the vinylidene fluoride polymer particles and the proportion of the alkyl acrylate in the monomer mixture being less than 80% by weight, wherein the vinylidene fluoride polymer is obtained by emulsion polymerization and is a vinylidene fluoride/tetrafluoroethylene copolymer or a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene copolymer.
Dependencies are inferred from the claim text.