US 5,348,771 AGranted

Method of producing an oxygen barrier coating containing trimethoxysilyl functional pentadienoate

AssigneeDow Corning Corporation

InventorsChi-Long Lee, Ming-Hsiung Yeh

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Abstract

A composite films which exhibit low oxygen transmission rates. The film comprises a silane resin coated on a plastic substrate then cured by ultraviolet radiation. For the silane coating, this invention relies on a class of organosilicon compounds derived from 1) organohydrogensilanes or organohydrogensiloxanes and 2) propargyl esters of carboxylic acids containing a terminal aromatic hydrocarbon radical, where the carbopropynoxy group of the ester and the aromatic hydrocarbon radical are separated by at least two adjacent ethylenically unsaturated carbon atoms. If more than two of these carbon atoms are present they form a sequence of conjugated ethylenic double bonds which allows the polymer to cross-link upon exposure to ultraviolet radiation.

Claims8

Dependent claims

A method for producing a silane coated substrate, comprising:

(I) coating a plastic substrate with a silane solution comprising
(A) an organosilicon compound selected from the group consisting of silanes corresponding to the molecular formula
Q(R.sup.1 O).sub.3 Si
where Q represents the radical
R.sup.2 (CH.dbd.CH).sub.n --CH.dbd.CR.sup.3 C(O)R.sup.5 --,
each R.sup.1 is individually selected from the group consisting of unsubstituted monovalent. hydrocarbon radicals, R.sup.2 represents an aryl, alkoxyaryl or alkaryl radical, R.sup.3 is --C.dbd.N or --C(O)OR.sup.4 where R.sup.4 is hydrogen or an unsubstituted monovalent hydrocarbon radical selected from the same group as R.sup.1, R.sup.5 is O(CH.sub.2).sub.a CH.dbd.CH-- or --NR.sup.6 --(CH.sub.2).sub.b --, R.sup.6 is a hydrogen or hydrocarbon radical having from 1 to 6 carbon atoms, a is 1 to 5, b is 3 to 6, and n is 0 or a positive integer, with the proviso that n can be 0 only when R.sup.2 represents a naphthyl radical;
(B) itaconic acid;
(C) water;
and
(D) a solvent;
and
(II) curing the silane solution to a silicone resin with ultraviolet light.

9 more elements

Dependencies are inferred from the claim text.