Fixation of heavy metals, mercury recovery and dioxins destruction in municipal solid waste incinerator ash

In a process for the stabilization of heavy metals-containing fly ash obtained by subjecting flue gas to particulate separation, which process comprises forming a mixture of the fly ash and a calcium-containing material, said calcium-containing material being present in the mixture so as to provide a weight ratio of calcium to fly ash from about 0.04 to about 0.5:1, heating the mixture to a temperature in the range of from about 475.degree. C. to about 650.degree. C. and maintaining said temperature for a period of time from about 30 minutes to about five hours while in the presence of an oxygen-containing gas to produce a thermally treated fly ash and a purge gas, the improvement for (1) volatilizing and subsequently recovering any mercury which may be contained in the fly ash;

• (2) destroying any dioxins which may be contained in the fly ash and (3) preventing any elemental arsenic and selenium which may be contained in the fly ash from volatilizing and subsequently contaminating the purge gas comprising:
• (a) narrowing said temperature range from about 475 .degree. C.-650.degree. C. to about 475.degree. C.-600.degree. C.;
• (b) separating the thermally treated fly ash from the purge gas;
• and
• (c) cooling the separated purge gas to a temperature below 357.degree. C. in order to condense out and recover at least a portion of the mercury.