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US 5,347,042 AGranted
Optically active sulphur-containing amino acid derivatives, their preparation, their polymerisation to give optically active polymers and the use thereof
AssigneeBayer Aktiengesellschaft
InventorsMichael Grosse-Bley, Bruno Bomer, Rolf Grosser, Dieter Arlt, Walter Lange
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Abstract
The invention relates to new optically active sulphur-containing amino acid derivatives, a process for their preparation, their polymerisation to give optically active polymers and the use of these optically active polymers as adsorbents for chromatographic separation of racemates into enantiomers.
Claims5
An optically active sulphur-containing amino acid derivative of the formula ##STR11## in which R represents hydrogen, methyl or fluorine,
- R.sub.1 represents hydrogen or C.sub.1 -C.sub.4 -alkyl,
- R.sub.2 represents a straight-chain, branched or cyclic alkyl radical having up to 10 C atoms, or phenyl
- R.sub.3 represents a C.sub.10 -terpenyl radical, an adamantyl radical or a decahydronaphthyl radical, or represents a branched alkyl or cycloalkyl radical having from 2 to 20 C atoms, which is optionally mono-, di- or trisubstituted by halogen, alkoxy having 1 to 4 C atoms, or C.sub.3 -C.sub.12 -cycloalkyl, wherein the aryl and cycloalkyl radicals are optionally substituted by C.sub.1 -C.sub.4 -alkyl, and
- A represents a methylene or dimethylene group which is optionally mono- or di-C.sub.1 -C.sub.4 -alkyl-substituted.
1 more element
Dependencies are inferred from the claim text.