Blowing agents of the tetrazoles and their derivatives
AssigneeToyo Kasei Kogyo Company Limited
InventorsAtsuhiro Onishi, Koichi Matsunami, Masanao Ebara, Hiroaki Tanaka
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Abstract
Blowing agents of tetrazoles and their derivatives which have a melting point over 200.degree. C. and are used to manufacture the high quality foaming thermoplastic synthetic resin moldings, especially engineering or superengineering plastic moldings and said blowing agents generate no harmful gases and do not cause the deterioration of the thermoplastic synthetic resin moldings.
Claims7
In a process for the production of cellular products which comprises incorporating a blowing agent into rubber or a synthetic polymer and then heating to activate the blowing agent, the improvement which comprises using as the blowing agent tetrazole compounds represented by the formulae:
- ##STR5## where:
- R and R.sub.1 are the same or different and are OH, COOH, SO.sub.3 H, NO.sub.2, halogen and NR.sub.4 R.sub.5 wherein R.sub.4 and R.sub.5 are each H or C.sub.1 -C.sub.4 alkyl or R and R.sub.1 are phenyl, benzyl, or phenethyl substituted or substituted by 1 to 3 halogens, OH, NO.sub.2, COOH and NR.sub.4 R.sub.5 wherein R.sub.4 and R.sub.5 are as defined above, R.sub.2 is H, OH, COOH, SO.sub.3 H, NO.sub.2, halogen or NR.sub.4 R.sub.5 wherein R.sub.4 and R.sub.5 are as defined above, C.sub.1 to C.sub.6 alkyl, C.sub.3 to C.sub.6 cycloalkyl or C.sub.2 to C.sub.6 alkenyl, unsubstituted or substituted by C.sub.1 to C.sub.6 alkyl, OH, COOH, SO.sub.3 H, NO.sub.2, halogen or NR.sub.4 R.sub.5 wherein R.sub.4 and R.sub.5 are as defined above or R.sub.2 is phenyl, benzyl or phenethyl unsubstituted or substituted by 1 to 3 halogens, OH, NO.sub.2 or NR.sub.4 R.sub.5, wherein R.sub.4 and R.sub.5 are as defined above, C.sub.1 to C.sub.4 alkyl and esters or amides of lower carboxylic acids;
- M is Ca, Cu, Zn, Mn, Fe, Co, Ni or Ba and Z is a univalent inorganic or organic group which binds to or forms a salt with M.
Dependencies are inferred from the claim text.