Process for making graft propylene polymers
AssigneeQuantum Chemical Corporation
InventorsLeslie Wild, James A. Hinnenkamp, Biau-Hung Chang, Webster W. Kiang
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AssigneeQuantum Chemical Corporation
InventorsLeslie Wild, James A. Hinnenkamp, Biau-Hung Chang, Webster W. Kiang
Estimating the term…
A process for making a graft propylene copolymer in which a propylene polymer, selected from the group consisting of propylene homopolymers and propylene copolymers, is contacted with a polymerizable, unsaturated carboxylic acid or acid derivative in the presence of a coagent, having the structural formula (CH.sub.2 .dbd.CR.sup.1 CR.sup.2 R.sup.3.sub.x R, where R.sup.1, R.sup.2 and R.sup.3 are the same or different and are hydrogen, hydrocarbyl, halogen or a heterocyclic radical; x is an integer of 2 to 4; and R is a radical containing at least one atom of oxygen, nitrogen, sulfur, phosphorus or silicon having a valence equal to the value of x, and a free radical generating compound. This contact occurs at a temperature above both the melting point of the propylene polymer and the decomposition temperature of the free radical generating compound.
A continuous melt process for making a graft copropylene copolymer comprising contacting a propylene polymer selected from the group consisting of homopolymers of propylene and an .alpha.-olefin, wherein said .alpha.-olefin comonomer contains 2 to 12 carbon atoms and is present in a concentration of between about 0.5% and about 40%, said percentages being by weight, based on the total weight of the copolymer, and propylene copolymers with at least one polymerizable, ethylenically unsaturated carboxylic acid or acid derivative in the presence of a coagent having the structural formula (CH.sub.2 .dbd.CR.sup.1 --CR.sup.2 --R.sup.3).sub.x R, where R.sup.1, R.sup.2 and R.sup.3 are the same or different and are hydrogen, hydrocarbyl, halogen or a heterocyclic radical;
A continuous melt process of maleating a propylene polymer, said propylene polymer selected from the group consisting of a propylene homopolymer, a propylene-ethylene random copolymer and a propylene-ethylene impact copolymer, wherein said copolymer includes ethylene in a concentration of between 0.5% and about 40%, said percentage being by weight, based on the total weight of the copolymer, comprising contacting a propylene polymer with maleic anhydride in the presence of a coagent having the structural formula (CH.sub.2 .dbd.CR.sup.1 --CR.sup.2 --R.sup.3).sub.x R, where R.sup.1, R.sup.2 and R.sup.3 are the same or different and are hydrogen or C.sub.1 -C.sub.4 alkyl;
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