Process for making graft propylene polymers
AssigneeQuantum Chemical Corporation
InventorsBiau-Hung Chang, Leslie Wild, James A. Hinnenkamp
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AssigneeQuantum Chemical Corporation
InventorsBiau-Hung Chang, Leslie Wild, James A. Hinnenkamp
Estimating the term…
A process for making a graft propylene copolymer in which a propylene polymer, selected from the group consisting of propylene homopolymers and propylene copolymers, is contacted with a polymerizable, unsaturated carboxylic acid or acid derivative in the presence of a coagent, said coagent selected from the group consisting of a first compound having the structural formula ##STR1## where R is a hydrocarbyl or a radical containing at least one atom of oxygen, sulfur, nitrogen, phosphorus or silicon; R.sup.1 is hydrogen or C.sub.1 -C.sub.12 alkyl or aryl; and x is an integer of 1 to 4, and a second compound having the structural formula ##STR2## where R' is a hydrocarbyl or a radical containing at least one atom of oxygen, sulfur, nitrogen, phosphorus or silicon; R.sup.2 is hydrogen or C.sub.1 -C.sub.1 2 alkyl or aryl; and y is an integer of 2 to 4, and a free radical generating compound. This contact occurs at a temperature above both the melting point of the propylene polymer and the decomposition temperature of the free radical generating compound.
A process for making a graft propylene copolymer comprising contacting a propylene polymer, said propylene polymer selected from the group consisting of propylene homopolymers and propylene copolymers, with at least one polymerizable, ethylenically unsaturated carboxylic acid or acid derivative in the presence of a coagent, said coagent, present in a concentration of between about 0.01% and about 30% by weight, based on the weight of the propylene polymer, selected from the group consisting of a first compound having the structural formula ##STR7## where R is a hydrocarbyl or a radical containing at least one atom of oxygen, sulfur, nitrogen, phosphorus or silicon;
A process of maleating a propylene polymer comprising contacting a propylene polymer with maleic anhydride in the presence of a coagent, said coagent present in a concentration of between about 0.01% and bout 30% by weight, based on the weight of the propylene polymer, selected from the group consisting of a first compound having the structural formula ##STR9## where R is C.sub.1 -C.sub.18 alkyl, and a second compound having the structural formula ##STR10## where R' is an alphatic hydrocarbyl containing 2 to 6 carbon atoms;
Dependencies are inferred from the claim text.