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US 5,344,877 AGranted
Molding material from a particulate graft polymer
AssigneeBASF SE
InventorsWolfgang Fischer, Norbert Guentherberg, Norbert Niessner, Karl Ruppmich, Friedrich Seitz
Life of this patent
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Abstract
A molding material from a particulate graft polymer which consists of A: a grafting base A based on an acrylate rubber and B: a graft B of B1: from 40 to 89.9% by weight of at least one vinylaromatic monomer B1 B2: from 10 to 49.9% by weight of at least one polar, coplymerizable, ethylenically unsaturated monomer B2 B3: from 0.1 to 20% by weight of at least one monomer B3 containing one or more acidic groups.
Claims2
A molding material consisting essentially of
- (i) from 1-50% by weight of a particulate graft polymer of
- A:
- a grafting base (A) based on
- A1:
- an acrylate rubber having a glass transition temperature below 0.degree. C. the acrylate rubber consisting of
- A11:
- from 75 to 99.8% by weight of at least one alkyl acrylate (A11) where the alkyl radical is of 1 to 8 carbon atoms
- A12:
- from 0.1 to 5% by weight of at least one polyfunctional crosslinking monomer (A12) which contains at least two ethylene double bonds and is not conjugated in the 1,3-position, and
- A13:
- from 0.1 to 20% by weight of at least one monomer (A13) which is ethylenically unsaturated and contains a tertiary amino group in the molecule, or based on
- A2:
- a diene rubber (A2) having a glass transition temperature below 0.degree. C. wherein the diene rubber is obtained from conjugated diene monomers, the diene rubber consisting of
- A21:
- at least 50% by weight of one or more dienes (A21),
- A22:
- up to 50% by weight of at least one copolymerizable ethylenically unsaturated monomer (A22), and
- A23:
- from 0.1 to 15% by weight of at least one monomer (A23) which is ethylenically unsaturated and contains a tertiary amine group in the molecule, and
- B:
- a graft (B) of
- B1:
- from 40 to 89.9% by weight of at least one vinylaromatic monomer (B1),
- B2:
- from 10 to 49.9% by weight of at least one polar copolymerizable ethylenically unsaturated monomer (B2),
- B3:
- from 0.1 to 20% by weight of at least one monomer (B3) which is ethylenically unsaturated and contains carboxyl or sulfo groups, and (ii) from 50 to 90% by weight of at least one matrix polymer obtained from ethylenically unsaturated monomers, which polymer has a glass transition temperature of more than 25.degree. C.
24 more elements
Dependencies are inferred from the claim text.