Water-dilutable binder mixtures based on alkyd resins and poly-n-acyl alkyleneimines
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsUlrich Eicken, Brigitte Hase, Manfred Gorzinski, Wolfgang Gress, Norbert Stork
Life of this patent
Estimating the term…
Abstract
This invention includes new water-dilutable binder mixtures based on alkyd resins modified by poly{ethylene glycol} and poly{N-acyl alkylene imines}, a process for preparing such binder mixtures, and the use of such binders in oxidatively drying paints and varnishes.
Claims19
Water-dilutable binder mixtures that are suitable for oxidatively drying paints, said binder mixtures comprising alkyd resins in which polyethylene glycol is incorporated and of which the residual acid groups have been at least partly neutralized by addition of bases, wherein the improvement comprises the presence in the binder mixtures of poly-N-acyl alkyleneimines prepared by cationic polymerization of at least two chemically distinct types of monomers corresponding to general formula I:
- ##STR3## in which Z is a direct bond or the group ##STR4## where R.sup.5 and R.sup.6 may be the same or different and represent H or alkyl containing up to 2 carbon atoms,
- R.sup.1 to R.sup.4 may be the same or different and represent H, or an aromatic radical or aliphatic radical, each containing up to 8 carbon atoms, and
- R.sup.7 is an aromatic or aliphatic radical, attached by carbon, containing up to 21 carbon atoms,
- wherein from 5 to 50% by weight of the monomers corresponding to general formula I have an aromatic radical as R.sup.7, from 25 to 95% by weight of the monomers corresponding to general formula I have an olefinically unsaturated radical as R.sup.7, and not more than 25% by weight of the monomers corresponding to general formula I have a saturated alkyl group as R.sup.7.
Dependencies are inferred from the claim text.