Method for selective removal of organometallic and organosilicon residues and damaged oxides using anhydrous ammonium fluoride solution
AssigneeAdvanced Chemical Systems International Incorporated
InventorsBill Bowden, Debbie Switalski
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Abstract
A method for selectively removing oxidized organometallic residues, oxidized organosilicon residues, native oxides, and damaged oxides created in plasma-etching through emersion of plasma-etched silicon wafers in a solution of anhydrous ammonium fluoride and a polyhydric alcohol, which is substantially free of hydrogen fluoride and water.
Claims10
A method for selectively removing organometallic residues, organosilicon residues, native silicon oxides, or damaged silicon oxides created in processing a semiconductor substrate from said semiconductor substrate, comprising contacting said semiconductor substrate with an etching solution for a time sufficient to remove said organometallic residues, organosilicon residues, native silicon oxides, or damaged silicon oxides from said semiconductor substrate, wherein
- (a) said etching solution comprises an anhydrous ammonium fluoride salt dissolved in a polyhydric alcohol, said anhydrous ammonium fluoride salt selected from the group consisting of anhydrous ammonium fluoride and anhydrous ammonium bifluoride and mixtures thereof, and
- (b) said etching solution contains less than about 4% by weight water and is free of added hydrogen fluoride.
Dependencies are inferred from the claim text.