Polishes for metal surfaces, based on dispersions, in organic solvents, of waxes and fluorinated materials selected from fluoroolefin copolymers and perfluoropolyoxyalkylene oils, wherein said polishes comprise a cationic emulsifier of general formula:
- R[--L--Q.sup.+ X.sup.- ].sub.t (I)
- where:
- R is a chain of perfluorooxyalkylene units containing from 1 to 3 carbon atoms, having an average molecular weight ranging from 400 to 2,000;
- L is a divalent organic group;
- t=1 or 2;
- Q=a polar organic group comprising N or P atoms as positive charge carriers, and having formula:
- ##STR10## A.sup.+ =a N or P atom;
- R.sub.1, R.sub.2, R.sub.3, like or different from one another, are alkyl groups containing from 1 to 12 carbon atoms, or, when A.sup.+ is P, they can be also aryl groups, or Q is an aromatic or aliphatic ring, either saturated or unsaturated, containing N or P atoms as positive charge carrier directly bound to the L group, in which such ring can optionally contain alkyl substituents and other heteroatoms selected from O and S;
- X.sup.- =anion.