Silver halide black & white light-sensitive material comprising spectrally sensitized silver halide grains containing rhodium in a specific amount
AssigneeKonica Corporation
InventorsMitsuhiro Okumura, Masataka Nakano, Yuji Tanaka
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Abstract
A silver halide black and white photographic light-sensitive material which is improved in pressure resistance and storage stability is disclosed comprising a support having thereon a silver halide emulsion layer comprising silver halide grains, wherein said silver halide grains contain rhodium in an amount of 10.sup.-8 to 10.sup.-5 moles per mol of silver halide; and said grains are spectrally sensitized with a combination of sensitizing dyes (GS-1) and (RS-1), each represented by the following formula: ##STR1##
Claims11
A silver halide black and white photographic light-sensitive printing material comprising a support having thereon a silver halide emulsion layer comprising silver halide grains, wherein said silver halide grains contain rhodium in an amount of 10.sup.-8 to 10.sup.-5 mols per mol of silver halide;
- and said grains are spectrally sensitized with a combination of sensitizing dyes [GS-1) and (RS-1), each represented by the following formula:
- ##STR11## wherein Z.sup.1 represents a group consisting of non-metal atoms necessary for forming an oxazole ring, a benzoxazole ring or a naphthoxazole ring, each of which may have a substituent;
- R.sup.1 and R.sup.2 each represent an alkyl group;
- R.sup.3 and R.sup.4 each represent a hydrogen atom, an alkyl group, an alkoxy group, a sulfo group, a sulfoalkyl group, a carboxy group or a halogen atom;
- ##STR12## wherein R.sup.1 and R.sup.2 each represent an alkyl group;
- Z.sup.1 and Z.sup.2 each represent a group consisting of non-metal atoms necessary for forming a benzene ring or a naphthalene ring;
- Z.sup.3 represents a group consisting of atoms necessary for forming a 6-membered hydrocarbon ring;
- m is an integer of 1 or 2;
- Y represents a sulfur atom or a selenium atom;
- and X represents an anion.
Dependencies are inferred from the claim text.