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US 5,250,081 AGranted
Smoke reducing additive for two-cycle engine lubricant-fuel mixture comprising the Hofmann decomposition products of a quaternary ammonium hydroxide
AssigneeExxon Research & Engineering Co.
InventorsJacob J. Habeeb, Christopher J. May
Life of this patent
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Abstract
A process for reducing smoke emitted from a two-cycle internal combustion engine wherein the engine is operated with a lubricant oil-fuel mixture containing certain quaternary ammonium hydroxides. A preferred quaternary ammonium hydroxide is tricapryl methyl quaternary ammonium hydroxide.
Claims9
A process for reducing smoke emitted from a two-cycle engine which comprises:
- (1) mixing a distillate fuel with from about 1 to about 3 vol. % of a lubricating oil basestock to produce a fuel-oil mixture
- (2) heating a quaternary ammonium hydroxide having the general formula:
- ##STR4## wherein R.sub.1 is a hydrocarbon radical or a hydroxy terminated radical having from 1 to 24 carbon atoms, R.sub.2 is a hydrocarbon radical having from 1 to 24 carbon atoms, and R.sub.3 and R.sub.4 are hydrocarbon radicals having from 4 to 24 carbon atoms, wherein R.sub.1, R.sub.2, R.sub.3, or R.sub.4 optionally contains a nitrogen atom, an oxygen atom, a sulfur atom or mixtures thereof, or a mixture of quaternary ammonium hydroxide having the general formula (I) to a temperature sufficient to decompose said quarternary ammonium hydroxide to the Hofmann decomposition products thereof,
- (3) adding to the fuel-oil mixture from about 0.1 to about 5 wt. % based on weight of lubricant in the fuel-oil mixture of an additive comprising the Hofmann decomposition products of the quarternary ammonium hydroxide, and
- (4) operating the two-cycle engine with the additive containing fuel-oil mixture.
2 more elements
Dependencies are inferred from the claim text.