Process for imaging multi-layer resist structure
AssigneeInternational Business Machines Corporation
InventorKaolin N. Chiong
Life of this patent
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Abstract
An image is provided by depositing a first layer of a photoresist containing a phenolic-formaldehyde novolak type polymer and an imidazole, benzimidazole, triazole, or indazoles to increase the solubility of the layer in aqueous alkaline developer after exposure to imaging radiation; depositing on the first layer a second layer of a photoresist containing a phenolic-formaldehyde novolak type polymer; the second layer having a lower degree of solubility in aqueous alkaline developer after exposure to imaging radiation; exposing the layers to imaging radiation; and developing the layers.
Claims12
A process for providing an image which comprises:
- depositing on a substrate a first layer of a positive photoresist comprising a phenolicformaldehyde novolak type polymer with a diazosensitizer and a compound selected from the group of imidazoles, benzimidzoles, triazoles, and indazoles, and mixtures thereof in an amount sufficient to increase the solubility of the layer in aqueous alkaline developer after exposure to imaging radiation;
- depositing on said first layer a second and different layer of a positive photoresist comprising a phenolic-formaldehyde novolak type polymer with a diazo-sensitizer wherein said second layer has a lower degree of solubility than said first layer in aqueous alkaline developer after exposure to imaging radiation;
- exposing said first layer of positive photoresist and said second layer of positive photoresist to imaging radiation in a predetermined pattern;
- and
- developing said first layer of positive photoresist and said second layer of positive photoresist to thereby remove the portions of said first layer and said second layer that were exposed to said imaging radiation.
Dependencies are inferred from the claim text.