Radiation curable liquid (meth) acrylated polymeric hydrocarbon maleate prepolymers and formulations containing same
AssigneeW. R. Grace & Co.
InventorLori J. Klinger
Life of this patent
Estimating the term…
Abstract
This invention is directed to a thermal or radiation curable prepolymer, formulations containing same and processes of using same, said prepolymer comprising a liquid meth(acrylate) terminated polymeric hydrocarbon maleate having pendant maleate groups. Said prepolymer either per se or formulated with mono- or multi-functional unsaturated monomers and either a thermal or photoinitiator on exposure to heat or UV or high energy ionizing radiation forms a cured material utilizable as a printing plate, coating, adhesive or sealant.
Claims16
A liquid thermal or radiation curable composition comprising a (meth)acrylate terminated, olefinically unsaturated maleate prepolymer having pendant maleate groups, said prepolymer having the formula P(Y)a wherein P is a homopolymer or copolymer of butadiene, isoprene, or chloroprene, a copolymer of butadiene, isoprene, or chloroprene with styrene, isobutylene, propylene, ethylene, acrylonitrile, acrylic acid, or neohexene, or corresponding partially hydrogenated polymers, a is one or more, and Y is a pendant or terminal group attached to P having the structure ##STR9## wherein R.sub.1 and R.sub.2 are each individually hydrogen, halogen, carboxy, linear or cyclic alkyl containing 1-20 carbon atoms, aryl, alkaryl and aralkyl containing 6-20 cargon atoms, R.sub.3 is hydrogen or methyl, X is --0--, --S--, or --NR--, R is hydrogen or alkyl of 1 to 6 carbon atoms, n is an integer from 1 to 6, and c has an average value of 0.1 to 1.0.
A process of forming a (meth)acrylate terminated, olefinically unsaturated, maleate prepolymer having pendant maleate groups which consists essentially of (a) reacting an olefinicallly unsaturated polymer selected from the group consisting of a homopolymer or copolymer of butadiene, isoprene, or chloroprene, a copolymer of butadiene, isoprene, or chloroprene wit styrene, isobutylene, propylene, ethylene, acrylonitrile, acrylic acid, or neohexene, and corresponding partially hydrogenated polymers and containing terminal functional group members selected from the group consisting of amine, hydroxyl and thiol with a member of the group consisting of an unsaturated anhydride of the general formula:
- ##STR11## wherein R.sub.1 and R.sub.2 are individually a member of the group consisting of hydrogen, halogen, carboxyl, linear or cyclic alkyl containing 1-20 carbon atoms, aryl, alkaryl and aralkyl containing 6 to 20 carbon atoms and the corresponding di-esters and di-acids for a time sufficient to form an olefinically unsaturated maleat polymer having terminal carboxyl groups, (b) reacting said terminal carboxyl groups with a reagent containing a (meth)acrylate group and a group selected from oxirane and axiridine to form a (meth)acrylate terminated, olefinically unsaturate,, maleate polymer having pendant active hydrogen containing groups, said reaction being carried out at a temperature in the range 25.degree.-200.degree. C., and, thereafter, (c) reacting said active hydrogen containing groups with about 0.1 to 0.8 equivalents of said unsaturated anhydride.
Dependencies are inferred from the claim text.