Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers
AssigneeMinnesota Mining and Manufacturing Company
InventorsJames N. Kellen, Charles W. Taylor
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AssigneeMinnesota Mining and Manufacturing Company
InventorsJames N. Kellen, Charles W. Taylor
Estimating the term…
A pressure-sensitive adhesive is provided which is a copolymer of an acrylate monomer which contributes to the visco-elastic properties of the copolymer and a copolymerizable mono-ethylenically unsaturated aromatic ketone comonomer free of ortho-aromatic hydroxyl groups by means of which the copolymer can be crosslinked upon exposure to ultraviolet radiation such that the amount of crosslinking comonomer and the degree of polymerization of the copolymer are controlled to obtain a creep compliance value of at least about 1.2.times.10.sup.-5 cm.sup.2 /dyne, the adhesive exhibits an enhanced level of initial adhesion when applied to skin but resists objectionable adhesion build-up over time. A preferred crosslinking ethylenically unsaturated hydroxyl-free aromatic ketone comonomer is p-acryloxybenzophenone.
A composition useful as a pressure-sensitive skin adhesive comprising a crosslinked copolymer comprised of A monomers and PX monomers, wherein:
A composition in accordance with claim 2 wherein Y is selected from the group consisting of a covalent bond, an oxygen atom, an amine group, an oxyalkyleneoxy group, and a carbamoylalkyleneoxy group.
A precursor composition useful in making a pressure-sensitive skin adhesive, the precursor composition comprising an uncrosslinked copolymer comprised of A monomers and PX monomers, wherein:
Dependencies are inferred from the claim text.