Heat developable light-sensitive material with protective layer
AssigneeFuji Photo Film Co., Ltd.
InventorsToshiaki Aono, Koichi Nakamura
Life of this patent
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Abstract
A heat developable light-sensitive material is disclosed which is provided with a protective layer comprising, as a major constituent, a nonionic, hydrophilic polymer. On heat developing the light-sensitive material, a mobile dye image is formed which can be transferred to a dye fixing material superposed on the light-sensitive material. After the transfer of the dye image, the light-sensitive material can be readily separated from the dye fixing material due to the presence of the protective layer, and thus a sharp image can be formed in the dye fixing material.
Claims10
A dye image forming process, comprising:
- heat developing a heat developable light-sensitive silver halide, a hydrophilic binder and a dye providing substance by heating after imagewise exposure or simultaneously with imagewise exposure to imagewise form a mobile dye,
- transferring said mobile dye from said heat developable light-sensitive material to a dye fixing material comprising a support having thereon a dye fixing layer, a hydrophilic binder and a mordant by heating after the heat developing or simultaneously with the heat developing in the presence of a hydrophilic thermal solvent which is contained in the dye fixing layer or a layer adjacent thereto and is coated in an amount of 20-200% by weight based on the total coating amount of the layers of the heat developable light-sensitive material and the dye fixing material, and
- peeling said dye fixing material form said heat developable light-sensitive material,
- said heat-developable light-sensitive material further comprising a protective layer on the side that said heat developable light-sensitive material contacts with said dye fixing material containing gelatin and at least one nonionic hydrophilic polymer having a molecular weight range of 2,000 to 1,000,000 which is selected from the following group (i) or (ii):
- (i) a nonionic hydrophilic polymer represented by the general formula (I):
- ##STR20## wherein x is 0 to 100 mol%, y is 0 to 100 mol%, the total of x and y is 100 mol%, R.sub.1 is hydrogen or alkyl, R.sub.2 is hydrogen or alkyl, R is --OH, carbamoyl or a 5- or 6-membered nitrogen-containing heterocyclic group and R' is --OH, carbamoyl or a 5- or 6-membered nitrogen-containing heterocyclic group;
- or
- (ii) a nonionic hydrophilic polymer selected from the group consisting of:
- ##STR21## wherein n represents the degree of polymerization, dextran,
- graft polymers of dextrin and ethylene oxide,
- graft polymers of dextrin and propylene oxide,
- poly(N-vinyl)pyrrolidone,
- grafted gelatin,
- hydroxyethyl cellulose,
- hydroxypropylmethyl cellulose phthalate,
- a polymer having the following repeating unit:
- ##STR22## starch, or pullulan.
Dependencies are inferred from the claim text.