Manufacture of phenyl esters
OwnerAnil B. Goel, Robert A. Grimminventors
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Abstract
A process is described for the manufacture of aryl esters such as phenyl esters by liquid phase reaction of an aromatic compound such as benzene with molecular oxygen in the presence of a carboxylic acid preferably having 6 or more carbon atoms over a catalyst composed essentially of a compound of palladium and an antimony compound wherein the aromatic compound is added continuously to the reaction and water formed in the reaction is rapidly and continuously removed from the reaction zone.
Claims8
An oxidation process for the manufacture of phenyl esters consisting essentially of contacting a reaction mixture of benzene, a mono or poly-carboxylic acid having 6 or more carbon atoms and molecular oxygen in the liquid phase at a temperature in the range of 100.degree. to 300.degree. C. with a catalyst consisting of a palladium carboxylate and an antimony carboxylate wherein the benzene is added continuously to the reaction mixture and the water formed in the process is removed continuously from the reaction mixture as the phenyl ester is formed.
Dependencies are inferred from the claim text.