Anti-wear additives in alkanol fuels
AssigneeExxon Research & Engineering Co.
InventorsRaymond C. Craig, Jerome Panzer, Max J. Wisotsky, Morton Beltzer
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Abstract
An additive for alkanol-containing fuels is disclosed which has improved lubricating and wear characteristics. The additive comprises an ester of a monocarboxylic or polycarboxylic acid and a polyhydric alcohol.
Claims25
A fuel composition having improved wear reduction and lubricity properties and comprising a major amount of monohydroxy alkanol having from 1 to 5 carbon atoms and an effective wear reducing amount of an additive which is an ester of a monocarboxylic or polycarboxylic acid and a polyhydric alcohol, said acid having about 2 to about 3 carboxylic acid groups and about 24 to about 65 carbon atoms, said alcohol having about 2 to about 10 hydroxyl groups and about 2 to about 90 carbon atoms and said ester having at least two free hydroxyl groups.
The fuel composition of claim 27 wherein said polycarboxylic acid is a dimer of linoleic or oleic acid or mixtures thereof and said glycol is ethylene or diethylene glycol.
A method of reducing wear in an engine operating on fuel containing a major amount of a monohydroxy alkanol having from 1 to 5 carbon atoms comprising adding an effective wear reducing amount of an additive which is an ester of a monocarboxylic or polycarboxylic acid and a polyhydric alcohol, said acid having about 2 to about 3 carboxylic acid groups and about 8 to about 65 carbon atoms, said alcohol having about 2 to about 10 hydroxyl groups and about 2 to about 90 carbon atoms and said ester having at least two free hydroxyl groups.
A fuel composition having improved wear reduction and lubricity properties and comprising a major amount of a monohydroxy alkanol having from 1 to 5 carbon atoms and an effective wear reducing amount of an additive which is an ester of a monocarboxylic or polycarboxylic acid and a polyhydric alcohol, said acid is a dimer acid of a conjugated fatty acid wherein the carboxyl groups are separated from each other by about 16 to about 22 carbon atoms, said alcohol having about 2 to about 10 hydroxyl groups and about 2 to about 90 carbon atoms and said ester having at least two free hydroxyl groups.
Dependencies are inferred from the claim text.