Color-forming sulfonamidodiphenylamines and corresponding sulfonimide dyes
AssigneeEastman Kodak Company
InventorsRolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz, Max H. Stern
Life of this patent
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Abstract
Color-forming para-sulfonamidodiphenylamines and their corresponding sulfonimide dyes are useful in imaging materials. The color-forming sulfonamidodiphenylamines are prepared by condensation reactions. The corresponding sulfonimide dyes are formed by oxidation of the color-forming sulfonamidodiphenylamines by means of a suitable oxidizing agent, such as the oxidized form of a cross-oxidizing silver halide developing agent.
Claims6
A color-forming sulfonamidodiphenylamine which is represented by the formula:
- ##STR54##
A color-forming para-sulfonamidodiphenylamine represented by the formula:
- ##STR55## wherein:
- R.sup.21 is alkoxy containing 1 to 20 carbon atoms or ##STR56## R.sup.22 is hydrogen or ##STR57## R.sup.23 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, aryloxy containing 6 to 12 carbon atoms or NH--R.sup.27 ;
- R.sup.24 is hydrogen or alkyl containing 1 to 20 carbon atoms;
- R.sup.25 is hydrogen, alkyl containing 1 to 20 carbon atoms, or aryl containing 6 to 15 carbon atoms;
- R.sup.26 is alkyl containing 1 to 20 carbon atoms, cycloalkyl containing 5 to 20 carbon atoms, or aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, aryloxy containing 6 to 12 carbon atoms or NH--R.sup.28 ;
- R.sup.27 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, or aryloxy containing 6 to 12 carbon atoms;
- and
- R.sup.28 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, or aryloxy containing 6 to 12 carbon atoms.
A sulfonimide dye which is represented by the formula:
- ##STR59##
A sulfonimide dye represented by the structure:
- ##STR60## wherein:
- R.sup.58 is alkoxy containing 1 to 20 carbon atoms or ##STR61## R.sup.59 is hydrogen or ##STR62## R.sup.60 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, aryloxy containing 6 to 12 carbon atoms or NH--R.sup.64 ;
- R.sup.61 is hydrogen or alkyl containing 1 to 20 carbon atoms;
- R.sup.62 is hydrogen, alkyl containing 1 to 20 carbon atoms, or aryl containing 6 to 15 carbon atoms;
- R.sup.63 is alkyl containing 1 to 20 carbon atoms, cycloalkyl containing 5 to 20 carbon atoms, or aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, aryloxy containing 6 to 12 carbon atoms or NH--R.sup.65 ;
- R.sup.64 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms, aryloxy containing 6 to 12 carbon atoms;
- and
- R.sup.65 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 12 carbon atoms, alkoxy containing 1 to 4 carbon atoms or aryloxy containing 6 to 12 carbon atoms.
A sulfonimide dye which is represented by the structure:
- ##STR63##
Dependencies are inferred from the claim text.