Silver halide color photographic materials with diffusible dye for improving graininess
AssigneeFuji Photo Film Co., Ltd.
InventorsKei Sakanoue, Shigeo Hirano, Keiichi Adachi
Life of this patent
Estimating the term…
Abstract
In a silver halide color photographic material is disclosed. The material is comprised of a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, and a red-sensitive silver halide emulsion layer. The granularity of the material is improved by incorporating a non-diffusible coupler capable of forming a properly smearing diffusible dye by causing a reaction with the oxidation product of a color developing agent and a colorless competing compound capable of capturing the oxidation product of a color developing agent in at least one of the foregoing silver halide emulsion layers.
Claims10
A silver halide color photographic material comprising a support having formed thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, and a red-sensitive silver halide emulsion layer, at least one of said emulsion layers containing a non-diffusible coupler which forms a properly smearing diffusible dye upon reaction with the oxidation product of a color developing agent together with a substantially colorless competing compound which captures the oxidation product of a color developing agent wherein the colorless competing compound is represented by the general formula (CI) ##STR19## wherein X is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or an --OZ group, wherein Z represents a hydrogen atom, an acyl group, and alkoxycarbonyl group, a carbamoyl group, a sulfonyl group, an alkyl group containing 1 to 20 carbon atoms, and an alkenyl group containing 2 to 22 carbon atoms or a methallyl group;
- R.sup.21, R.sup.22 and R.sup.23 independently represent a hydrogen atom, a halogen atom, a cyano group, --SO.sub.2 R.sup.24, --COR.sup.24, a substituted or unsubstituted alkyl group containing 1 to 30 carbon atoms, a substituted or unsubstituted akenyl group containing 2 to 30 carbon atoms, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted aryl group;
- and wherein R.sup.24 is a hydroxy group, a substituted or unsubstituted aryl group containing 1 to 30 carbon atoms, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted amino group.
Dependencies are inferred from the claim text.