Pesticidal symmetrical bis-sulfenylated-bis carbamate compounds
AssigneeUnion Carbide Corporation
InventorThemistocles D. J. D'Silva
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Abstract
Bis-sulfenylated bis-carbamate compounds exhibit activity against insect and mite pests.
Claims32
A compound of the formula:
- ##STR39## wherein:
- X is:
- A. a substituted or unsubstituted divalent alkylene, alkenylene, alkynylene, monocyclic arylene, bicyclic arylene, biphenylene or a divalent alkylene chain which includes one oxygen, sulfur, sulfinyl, sulfonyl or nitrogen, wherein the permissible substitutents are one or more alkyl, fluoro, nitro, chloro, or bromo groups.
- B. a divalent organic radical of the formula:
- ##STR40## wherein:
- Y is oxygen, sulfur, sulfinyl, sulfonyl, alkylene, haloalkylene, alkenylene, or haloalkenylene;
- R.sub.1 is alkyl having from one to four carbon atoms;
- R.sub.2 is:
- ##STR41## wherein R.sub.3 is hydrogen alkyl, alkylthio, alkylsulfinyl, alkylsulfonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl or cyano;
- R.sub.4 is alkyl, alkylthio, alkylsulfinyl, alkylsulfonyl, aminocarbonyl, alkylaminocarbonyl dialkylaminocarbonyl or alkanoyl, all of which may be unsubstituted or, except for aminocarbonyl substituted with one or more cyano, amido, nitro, alkylthio, alkylsulfonyl or alkylsulfinyl;
- A is a divalent chain having from 2 to 24 aliphatic carbon atoms completing a 2-oximino-1,4 dithiane, 2-oximino-1,3-dithiane, 4-oximino-1,3-dithiolane, 2-oximino-1,4-dioxane, 2-oximino-1,4-oxathiane, 2-oximino tetrahydro-1,4-thiazine-3-one, 2-oximino-1,3-dithiolane, 2-imino-4-oximino-1,3-dithiolane, 3-oximinothiophane, 2-oximinothiophane, 2-oximino-tetrahydro-1,4-oxazin-3-one, 2-oximino-1,3,5-trithiane, 4-oximino-1,3,5-oxadithiane, 2-oximino-1,3-thiazolidin-4-one, 5-oximino-1,3-thiazolidin-4-one or 2-oximino-tetrahydro-1,4-thiazine-5-one ring structure, wherein sulfur may be in any of its oxidation states.
1,2-Bis-[[N-methyl-N-[N'-(1-met hylthioethylideneiminooxycarbonyl)-N'-methylaminosulfenyl]carbamoyloxy]]ben zene.
1, 3-Bis-[[N-methyl-N-[N'-(1-methylthioethylideneiminooxycarbonyl)-N'-methylam inosulfenyl]carbamoyloxy]]benzene.
1,2-Bis-[[N-methyl-N-[N'-(1-met hylthioethylideneiminooxycarbonyl)-N'-methylaminosulfenyl]carbamoyloxy]]eth ane.
A compound of the formula:
- ##STR43## wherein X is:
- A. a substituted or unsubstituted divalent alkylene, monocyclic arylene, or a divalent alkylene chain which includes one oxygen or nitrogen, wherein the permissible substituents are one or more alkyl groups, or
- B. a divalent organic radical of the formula:
- ##STR44## wherein:
- Y is oxygen, sulfur, sulfinyl, sulfonyl, or alkylene;
- R.sub.1 is alkyl having from one to four carbon atoms;
- R.sub.2 is ##STR45## R.sub.3 is hydrogen, alkyl or dialkylaminocarbonyl;
- R.sub.4 is alkylthio or alkyl substituted with alkylthio.
A compound having the formula:
- ##STR46##
A compound having the formula:
- ##STR47##
A compound having the formula:
- ##STR48##
A compound having the formula:
- ##STR49##
A compound having the formula:
- ##STR50##
A compound having the formula:
- ##STR51##
Dependencies are inferred from the claim text.