US 4,400,329 AGranted

Process for the manufacture of thiochlorformates

AssigneeSociete Nationale des Poudres et Explosifs

InventorsJulien Deweerdt, Jacques Sala, Denis Souyri

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Abstract

According to the invention, phosgene is reacted with a mercaptan in the presence of a catalyst of the general formula: ##STR1## in which X=O or S and in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are, in particular, aliphatic, cycloaliphatic or aromatic groups or a hydrogen atom. The proportion of catalyst is 0.1 to 10 mol %, relative to the mercaptan, and the reaction is carried out at ambient temperature and at atmospheric pressure. The process, which can be made continuous, results in short residence times and in a high yield and a high purity. Thiochloroformates are applied essentially as intermediates for the synthesis of herbicidal compounds.

Claims8

Dependent claims

Process for the manufacture of thiochloroformates by reacting phosgene with a mercaptan in the presence of a catalyst, wherein a substituted urea or the reaction product of a substituted urea with phosgene is used as the catalyst and the urea has the formula ##STR3## in which X=O or S and in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are linear or branched C.sub.1 to C.sub.18 alkyl, C.sub.6 to C.sub.9 aryl, C.sub.7 to C.sub.10 alkaryl, C.sub.7 to C.sub.10 aralkyl, C.sub.2 to C.sub.5 alkenyl or hydrogen atoms, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 being all different or all the same at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 being other than hydrogen or alternatively R.sub.1 and R.sub.2 are joined to one another to form a polymethylene chain containing from 4 to 8 members, or R.sub.3 and R.sub.4 also forming with one another a polymethylene chain containing from 4 to 8 members.

Dependencies are inferred from the claim text.