Modification of ethylene/acrylate/carboxylic polymer
AssigneeE. I. Du Pont de Nemours and Company
InventorNicolas Brodoway
Life of this patent
Estimating the term…
Abstract
Elastomeric ethylene/alkyl acrylate/1,4-butenedioic acid ester copolymers are stabilized against variations in cure characteristics by reaction of such polymers with amines, perferably during isolation of such polymers. In addition, substantial increase in the molecular weight of such polymers is achieved if the amines are di- or polyamines.
Claims6
A process for increasing the hydrolytic stability and uniformity, and optionally increasing the molecular weight of random ethylene/methyl acrylate/1,4-butenedioic acid ester copolymer, said copolymer containing 0.5-10 weight percent 1,4-butenedioic acid ester, 40-62 weight percent methyl acrylate, and 28-59.5 weight percent ethylene, said process comprising heating said copolymer to a temperature of 140.degree.-200.degree. C. for a period of at least five minutes, and then contacting the heated copolymer in which the anhydride content is about 0.01-0.1 mole/kg of said heated copolymer with 0.01-0.1 equivalents of amine per kilogram of polymer wherein the amine consists of carbon, hydrogen and nitrogen atoms and is selected from the group consisting of monamines, polyamino compounds, compounds which generate such monoamines and polyamino compounds upon chemical reaction, and mixtures of the above.
Dependencies are inferred from the claim text.