Photopolymerizable compositions
AssigneeFuji Photo Film Co., Ltd.
InventorsSyunichi Kondo, Akihiro Matsufuji, Akira Umehara, Toshinao Ukai, Akira Sato
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AssigneeFuji Photo Film Co., Ltd.
InventorsSyunichi Kondo, Akihiro Matsufuji, Akira Umehara, Toshinao Ukai, Akira Sato
Estimating the term…
In a photopolymerizable composition comprising, as essential components, (A) a compound having at least one ethylenically unsaturated double bond capable of undergoing addition polymerization and (B) a photopolymerization initiator, the improvement which comprises that the photopolymerization initiator comprising a combination of (a) a 5-[(arenooxazol-2-ylidene)ethylidene]-2-thiohydantoin compound represented by the general formula (I) (a 5-[(substituted benzoxazol-2'-ylidene)ethylidene]-2-thiohydantoin compound) or (II) (a 5-[substituted naphthol(1,2-D)oxazol-2-ylidene)ethylidene]-2-thiohydantoin compound) and (b) a 2,4,6-substituted-1,3,5-triazine compound represented by the formula (III): ##STR1## wherein X represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, an aryl group, a substituted aryl group, an aryloxy group, an aralkyl group or a halogen atom; R.sup.1, R.sup.2 and R.sup.3 each represents an alkyl group, a substituted alkyl group, an alkenyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different; and R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different but at least one of which represents a mono-, di- or trihalogenomethyl group.
In a photopolymerizable composition comprising, as essential components, (A) a compound having at least one ethylenically unsaturated double bond capable of undergoing addition polymerization and (B) a photopolymerization initiator, the improvement wherein said component (A) is an oligoester acrylate or oligoester methacrylate obtained by esterification of acrylic or methacrylic acid, a polybasic acid and a polyol and said photopolymerization initiator consists essentially of a combination of (a) a 5-(substituted naphthol(1,2-D)oxazol-2-ylidene)ethylidene-2-thiohydantoin compound represented by formula (II) and (b) a 2,4,6-substituted-1,3,5-triazine compound represented by formula (III):
An imaging process for photopolymerizing a photopolymerizable composition comprising an oligoester acrylate or oligoester methacrylate obtained by the esterification of acrylic or methacrylic acid, a polybasic acid and a polyol and a photopolymerization initiator which consists essentially of a combination of (a) (a 5-(substituted naphthol(1,2-D)oxazol-2-ylidene)ethylidene-2-thiohydantoin compound) represented by formula (II) and (b) a 2,4,6-substituted-1,3,5-triazine compound represented by formula (III):
Dependencies are inferred from the claim text.