Process for producing trimellitic acid
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsTakashi Suzuki, Koichi Kitahara, Susumu Naito, Tomoji Tsuji
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AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsTakashi Suzuki, Koichi Kitahara, Susumu Naito, Tomoji Tsuji
Estimating the term…
Trimellitic acid is produced in higher yield by liquid phase air oxidation of pseudocumene in acetic acid as a solvent in the presence of cobalt, manganese, and bromine as a catalyst, where the oxidation is carried out at two stages comprising a first stage of reaction at a temperature of 110.degree. to 170.degree. C. and a second stage of reaction at a temperature of 180.degree. to 240.degree. C. while maintaining a reaction pressure under a condition of the following formula throughout the reaction: 1.20 Psolv.ltoreq.P.ltoreq.2.20 Psolv wherein P represents a reaction pressure as absolute pressure and Psolv represents a total vapor pressure of acetic acid and water present in a reaction system at a given reaction temperature.
A process for producing trimellitic acid by liquid phase air oxidation of pseudocumene in an acetic acid reaction medium in the presence of a catalyst consisting of of catalytic forms of cobalt, manganese and bromine, which comprises conducting the reaction at two stages comprising a first stage of reaction at a temperature of 110.degree. to 170.degree. C. and a second stage of reaction at a temperature of 180.degree. to 240.degree. C., while maintaining a reaction pressure under a condition of the following formula throughout the reaction:
Dependencies are inferred from the claim text.