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US 4,398,015 AGranted
Fiber-forming polyesters of aromatic ketohydroxy acids
AssigneeE. I. Du Pont de Nemours and Company
InventorAugust H. Frazer
Life of this patent
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Abstract
Homopolyesters and copolyesters of specific ketohydroxy acids and which exhibit melt-anisotropy and are melt-spinnable into oriented filaments that can be heat treated to high tenacity.
Claims9
Fiber-forming melt-spinnable polyester that is optically anisotropic in the melt and consists essentially of the following amounts of recurring units of the structural formulas:
- (a) 25-100 mol % ##STR5## and (b) 0-75 mol % ##STR6## wherein both of R.sup.1 and R.sup.2 are H, CH.sub.3 or Cl or R.sup.1 is H and R.sup.2 is CH.sub.3 or Cl;
- both of R.sup.3 and R.sup.4 are H, CH.sub.3 or Cl or R.sup.3 is H and R.sup.4 is CH.sub.3 or Cl;
- and
- Ar is m- or p-phenylene,
- provided, however, when the amount of (a) is 90-100 mol %, Ar is m-phenylene in at least 30% of the (a) units, and provided further, however, when the amount of (a) is 100 mol % and only one species of (a) is present, R.sup.1 and R.sup.2 are both Cl, and provided still further, however, in copolyesters consisting essentially of two or more different species of (a), only one of said species is substituted and R.sup.1 and R.sup.2 therein are Cl.
2 more elements
Dependencies are inferred from the claim text.