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US 4,398,012 AGranted
Transparent copolyamide from caprolactam, cyclic diamine and cyclic dicarboxylic acid
AssigneeAllied Corporation
InventorsRobert G. Merrill, Robert A. Lofquist, Gene C. Weedon, John C. Haylock, Ian C. Twilley
Life of this patent
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Abstract
This invention is a transparent alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from (1) a diamine or diisocyanate and (2) a diacid or (c) 11.2 to 19.6 weight percent para amino benzoic acid.
Claims11
A transparent, alcohol resistant, hot water resistant, thermoplastically formable copolymer of
- (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining
- (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from a (1) diamine or diisocyanate selected from the group consisting of ##STR4## and mixtures thereof, and a diacid selected from the group consisting of ##STR5## and mixtures thereof, wherein R.sub.1 is independently selected from the group consisting of --H, --CH.sub.3, CH.sub.2 CH.sub.3, ##STR6## and --CH.sub.2 CH.sub.2 CH.sub.3, R.sub.2 is independently selected from the group consisting of --H, --CH.sub.3 and --CH.sub.2 CH.sub.3, R.sub.3 is independently selected from the group consisting of --CH.sub.2 -- and --CH.sub.2 CH.sub.2 --, and R.sub.4 is independently selected from the group consisting of --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 -- and ##STR7## or (C) 11.2 to 19.6 weight percent of ##STR8## wherein said copolymer is thermoformable at a temperature greater than the glass transition temperature of the copolymer and withstands exposure to an alcohol for extended periods without becoming translucent, dissolving or flowing.
Dependencies are inferred from the claim text.