Novel polymerization catalyst and process for using same to polymerize olefins
AssigneeGulf Research & Development Company
InventorsHarold E. Swift, Richard W. Lunden
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AssigneeGulf Research & Development Company
InventorsHarold E. Swift, Richard W. Lunden
Estimating the term…
There is provided a solid, particulate, catalytic complex suitable for the stereospecific polymerization of olefins prepared by reducing TiCl.sub.4, contacting the resultant reduced solid with a complexing agent to obtain a treated solid and contacting the treated solid with TiCl.sub.4 in the presence of silica which has been treated with an aromatic ester. When such a catalyst complex is combined with a suitable activator to polymerize olefins, a high degree of stereospecificity is attained, the activity of the catalyst complex is reduced for polymerization control and the efficiency of the titanium employed is enhanced.
A process for the polymerization of olefins which comprises contacting said olefin at elevated temperatures and elevated pressures with an activator and a solid, particulate, catalyst complex prepared by a process comprising reducing TiCl.sub.4, containing the resultant reduced solid with a complexing agent to obtain a treated solid and contacting the treated solid with TiCl.sub.4 in the presence of silica which has been treated with an aromatic ester.
Dependencies are inferred from the claim text.